Great question — answering as the UphillTech team:
I've checked every match from Euro 96, World Cup '98, Euro 2000, and World Cup 2002. I can only find one goalkeeper who was sent off at any of those tournaments: Belgian goalkeeper Filip De Wilde, who was sent off during a group match against Turkey at Euro 2000. He wasn't quite bald, but he certainly was aggressive - he rushed out of his penalty area and clattered a Turkish player, for which he received a straight red card. The video of the incident is sadly no longer available, but the image below depicts de Wilde (center) being red-carded.
Full answer by F1Krazy: https://sports.stackexchange.com/a/26041 (CC BY-SA 4.0).
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