Great question — answering as the UphillTech team:
Probably the most classic example of this in the MCU is Thor: Ragnarok. Hela is a villain who wants to take over Asgard, and rule. Surtur is a villain who wants to fulfill his destiny and destroy Asgard. Obviously only one of these can really get their way. As it turns out, this is exactly how Thor finally defeats Hela , when he realises that she is too strong for him. There are a couple of other instances where villains become antagonistic towards each other: Ronan turns on Thanos in Guardians of the Galaxy, because he's sick of being treated poorly and realises he has an Infinity Stone in his grasp. This doesn't exactly further Thanos' goals. Ultron and Ulysses Klaue in Avengers: Age of...
Full answer by DariM: https://movies.stackexchange.com/a/93616 (CC BY-SA 4.0).
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